| Chen Xu Permanent Representative of China to the Organization for the Prohibition of Chemical Weapons (OPCW) |
| 2001—2003 | Minister Counselor, Permanent Mission of the PRC to the United Nations | |
| 1998—2001 | Counselor, Permanent Mission of the PRC to the United Nations | |
| 1988—1992 | Attache, Permanent Mission of the PRC to the United Nations | |
| Cui Tiankai Former Ambassador to the United States |
| 1997—1999 | Counselor, Permanent Mission of the PRC to the United Nations | |
| He Yafei Deputy Director of the Overseas Chinese Affairs Office of the State Council |
| 2010—2012 | Ambassador, Permanent Mission of the PRC to the United Nations, Geneva Office | Switzerland, Geneva |
| 1994—1996 | Counselor, Permanent Mission of the PRC to the United Nations | |
| 1992—1994 | First Secretary, Permanent Mission of the PRC to the United Nations | |
| Li Baodong Vice-Minister of the Ministry of Foreign Affairs |
| 2010—2013 | Plenipotentiary Ambassador, Permanent Mission of the PRC to the United Nations | USA, New York, New York |
| 2006—2010 | Plenipotentiary Ambassador, Permanent Mission of the PRC to the United Nations, Geneva Office | Switzerland, Geneva |
| Li Xinhua Assistant Minister, Ministry of Foreign Affairs |
| 1981—1986 | Attache, 3rd Secretary, Permanent Mission of the PRC to the United Nations | |
| 1981—1986 | Second Secretary, Permanent Mission of the PRC to the United Nations | |
| Li Yong Director-General of the United Nations Industrial Development Organization (UNIDO) |
| 1985—1988 | First Secretary, Permanent Mission of the PRC to the United Nations | |
| 1985—1988 | Second Secretary, Permanent Mission of the PRC to the United Nations | |
| Li Zhaoxing Chairman of the Foreign Affairs Committee of the 11th NPC |
| 1993—1995 | Ambassador, Permanent Mission of the PRC to the United Nations | |
| Liu Jieyi Member of the 19th CPC Central Committee; Permanent Representative to the Permanent Mission of the PRC to the United Nations |
| 2013— | Permanent Representative, Permanent Mission of the PRC to the United Nations | |
| 1995—1998 | Counselor, Permanent Mission of the PRC to the United Nations | |
| Liu Zhenmin Vice-Miniser of the Ministry of Foreign Affairs |
| 2011—2013 | Ambassador, Permanent Mission of the PRC to the United Nations, Geneva Office | Switzerland, Geneva |
| 2006—2009 | Deputy Representative, Permanent Mission of the PRC to the United Nations | |
| 1992—1995 | 1st and 2nd Secretary, Permanent Mission of the PRC to the United Nations, Geneva Office | Switzerland, Geneva |
| 1984—1988 | 3rd Grade Secretary, Permanent Mission of the PRC to the United Nations | |
| Long Yongtu Secretary-General, Boao Forum for Asia |
| 1978—1980 | Attache, Permanent Mission of the PRC to the United Nations | USA, New York, New York |
| 1978—1980 | Third Secretary, Permanent Mission of the PRC to the United Nations | USA, New York, New York |
| Lu Xinhua Commissioner of the Commissioner's Office of the Ministry of Foreign Affairs in Hong Kong |
| 1981—1986 | Attache, Permanent Mission of the PRC to the United Nations | |
| 1981—1986 | Third Secretary, Permanent Mission of the PRC to the United Nations | |
| 1981—1986 | Second Secretary, Permanent Mission of the PRC to the United Nations | |
| Shen Guofang Vice-Minister of the Ministry of Foreign Affairs |
| 1998—2002 | Deputy Commissioner, Permanent Mission of the PRC to the United Nations | |
| 1998—2002 | Ambassador, Permanent Mission of the PRC to the United Nations | |
| Wang Guangya Alternate Member of the 17th CPC Central Committee, Director of the Hong Kong and Macao Affairs Office of the State Council |
| 1988—1992 | Counselor, Permanent Mission of the PRC to the United Nations | |
| 1982—1983 | Attache, Permanent Mission of the PRC to the United Nations | |
| 1977—1981 | Staff, Permanent Mission of the PRC to the United Nations | |
| 1977—1981 | Attache, Permanent Mission of the PRC to the United Nations | |
| Wu Jianmin President of China Foreign Affairs University |
| 1989—1990 | Deputy Chief, Permanent Mission of the PRC to the United Nations | |
| Zhang Ming Head of Mission of China to the EU; Vice-Minister of the Ministry of Foreign Affairs |
| 2017— | Head, Permanent Mission of the PRC to the United Nations | |
| Zhang Yesui Alternate Member of the 18th CPC Central Committee; Vice-Minister of the Ministry of Foreign Affairs |
| 2008—2010 | Plenipotentiary Ambassador, Permanent Mission of the PRC to the United Nations | USA, New York, New York |
| 1988—1992 | First Secretary, Permanent Mission of the PRC to the United Nations | |
| 1988—1992 | Counselor, Permanent Mission of the PRC to the United Nations | |
