| Cui Tiankai Former Ambassador to the United States |
| 1981—1984 | Interpreter, United Nations, Secretariat | USA, New York, New York |
| Feng Cui Member of the 9th Session Chinese People's Political Consultative Conference, Standing Member of the 8th All-China Womens' Federation |
| 1998—2000 | Member, United Nations, Committee for Eliminating Discrimination against Women | |
| 1991—1996 | Counselor, United Nations, Chinese Delegation | |
| 1983—1991 | Interpreter, United Nations, Liaison Office, Chinese Department | |
| Fu Ying Director of 12th NPC Foreign Affairs Committee |
| 1992—1993 | Staff Member, United Nations, Transitional Authority | Cambodia, Phnom Penh |
| Li Baodong Vice-Minister of the Ministry of Foreign Affairs |
| 2010—2013 | Permanent Representative, United Nations | USA, New York, New York |
| 2006—2010 | Permanent Representative, United Nations, Geneva Office | Switzerland, Geneva |
| Li Daoyu President of the China International Public Relations Association |
| 1990—1993 | Ambassador of China, United Nations | USA, New York, New York |
| 1988—1990 | Assistant Foreign Minister, United Nations, Chinese Delegation | |
| 1983—1984 | Deputy Representative of China, United Nations, Geneva Office | Switzerland, Geneva |
| Li Hong Permanent Representative of China to the United Nations Economic and Social Commission for Asia and the Pacific |
| 2014— | Permanent Representative, United Nations, Economic and Social Commission for Asia and the Pacific | |
| Liu Huaqiu Member of the 16th CPC Central Committee |
| ???? | Vice-Chairman, United Nations, World Summit on Social Development, Chinese Preparatory Committee | |
| Liu Jiayi Member of the 19th CPC Central Committee; Secretary of the Shandong CPC Party Committee |
| 2011—2017 | Chairman, United Nations, Board of Auditors (UNBA) | |
| Liu Jieyi Member of the 19th CPC Central Committee; Permanent Representative to the Permanent Mission of the PRC to the United Nations |
| 1981—1987 | Interpreter, United Nations, Geneva Office | |
| Liu Xianfa Permanent Representative to UNEP |
| 2014— | Permanent Representative, United Nations, Environment Program (UNEP) | |
| Long Yongtu Secretary-General, Boao Forum for Asia |
| 1980—1986 | Official, United Nations, Asia Pacific Regional Cooperation Program | USA, New York, New York |
| Qiao Zonghuai Vice Minister of Foreign Affairs |
| 1998—2001 | Representative, United Nations, Geneva Office | Switzerland, Geneva |
| Qu Dongyu Vice-Minister of the Ministry of Agriculture; Director of the UN Food and Agriculture Organization (FAO) |
| 2019— | Director, United Nations, Food and Agriculture Organization (FAO) | |
| Wang Guangya Alternate Member of the 17th CPC Central Committee, Director of the Hong Kong and Macao Affairs Office of the State Council |
| 2003—2008 | Ambassador, United Nations | |
| Wu Dechang Academician of the Chinese Academy of Engineering, Chief Director of the China Toxicology Society |
| ???? | Deputy Representative, United Nations, Atomic Radiation Effectiveness Science Committee | |
| Wu Jianmin President of China Foreign Affairs University |
| 1996—1998 | Permanent Representative of China to the U.N., United Nations, Geneva Office | Switzerland, Geneva |
| 1996—1998 | Ambassador of China to the U.N., United Nations, Geneva Office | Switzerland, Geneva |
| 1985—1989 | Counselor for China, United Nations | USA, New York, New York |
| Yuan Longping Vice-Chairman of CPPCC Hunan Provincial Committee, Academician of Chinese Academy of Engineering |
| 1991—???? | International Chief Consultant, United Nations, Food and Agriculture Organization (FAO) | |
| Zha Peixin Chinese Ambassador to the United Kingdom of Great Britain and Northern Ireland |
| 1972—1973 | Staff Member, United Nations, Chinese Delegation | |
| Zhang Ming Head of Mission of China to the EU; Vice-Minister of the Ministry of Foreign Affairs |
| 2006—2009 | Permanent Representative, United Nations, Environment Program (UNEP) | |
| Zhang Yesui Alternate Member of the 18th CPC Central Committee; Vice-Minister of the Ministry of Foreign Affairs |
| 2008—2013 | Chairman on Duty, United Nations, Security Council | |
