| Cui Tiankai Vice-Minister of the Ministry of Foreign Affairs |
| 1981—1984 | Interpreter, United Nations, Secretariat | USA, New York, New York |
| Feng Cui Member of the 9th Session Chinese People's Political Consultative Conference, Standing Member of the 8th All-China Womens' Federation |
| 1998—2000 | Member, United Nations, Committee for Eliminating Discrimination against Women | |
| 1991—1996 | Counselor, United Nations, Chinese Delegation | |
| 1983—1991 | Interpreter, United Nations, Liaison Office, Chinese Department | |
| Fu Ying Vice-Minister of the Ministry of Foreign Affairs |
| 1992—1993 | Staff Member, United Nations, Transitional Authority | Cambodia, Phom Penh |
| Li Baodong Plenipotentiary Ambassador, Chinese Permanent Representative to the United Nations |
| 2010— | Permanent Representative, United Nations | USA, New York, New York |
| 2006—2010 | Permanent Representative, United Nations, Geneva Office | Switzerland, Geneva |
| Li Daoyu President of the China International Public Relations Association |
| 1990—1993 | Ambassador of China, United Nations | USA, New York, New York |
| 1988—1990 | Assistant Foreign Minister, United Nations, Chinese Delegation | |
| 1983—1984 | Deputy Representative of China, United Nations, Geneva Office | Switzerland, Geneva |
| Liu Huaqiu Member of the 16th CPC Central Committee |
| ???? | Vice-Chairman, United Nations, World Summit on Social Development, Chinese Preparatory Committee | |
| Liu Jiayi Member of the 17th CPC Central Committee; Auditor-General of the National Audit Office; Chairman of the United Nations Board of Auditors |
| 2011— | Chairman, United Nations, Board of Auditors (UNBA) | |
| Liu Jieyi Assistant Minister of Foreign Affairs, Deputy Director of the International Liaison Department of the CPC Central Committee |
| 1981—1987 | Interpreter, United Nations, Geneva Office | |
| Long Yongtu Secretary-General, Boao Forum for Asia |
| 1980—1986 | Official, United Nations, Asia Pacific Regional Cooperation Program | USA, New York, New York |
| Qiao Zonghuai Vice Minister of Foreign Affairs |
| 1998—2001 | Representative, United Nations, Geneva Office | Switzerland, Geneva |
| Wang Guangya Alternate Member of the 17th CPC Central Committee, Director of the Hong Kong and Macao Affairs Office of the State Council |
| 2003—2008 | Ambassador, United Nations | |
| Wu Dechang Academician of the Chinese Academy of Engineering, Chief Director of the China Toxicology Society |
| ???? | Deputy Representative, United Nations, Atomic Radiation Effectiveness Science Committee | |
| Wu Jianmin President of China Foreign Affairs University |
| 1996—1998 | Permanent Representative of China to the U.N., United Nations, Geneva Office | Switzerland, Geneva |
| 1996—1998 | Ambassador of China to the U.N., United Nations, Geneva Office | Switzerland, Geneva |
| 1985—1989 | Counselor for China, United Nations | USA, New York, New York |
| Yuan Longping Vice-Chairman of CPPCC Hunan Provincial Committee, Academician of Chinese Academy of Engineering |
| 1991—???? | International Chief Consultant, United Nations, Food and Agriculture Organization | |
| Zha Peixin Chinese Ambassador to the United Kingdom of Great Britain and Northern Ireland |
| 1972—1973 | Staff Member, United Nations, Chinese Delegation | |
| Zhang Yesui Plenipotentiary Ambassador to the United States |
| 2008— | Chairman on Duty, United Nations, Security Council | |