| 2008— | Vice-Chairman, 11th CPPCC, National Committee | |
| 2007— | Member, 17th CPC, Central Committee | |
| 2003—2008 | Vice-Chairman, 10th CPPCC, National Committee | |
| 2002—2007 | Member, 16th CPC, Central Committee | |
| 1997—2002 | Member, 15th CPC, Central Committee | |
| 1997—2003 | Chairman, Autonomous Region People's Government Guangxi Zhuang Autonomous Region | |
| 1996—2002 | Deputy Secretary, CPC, Autonomous Regional Committee Guangxi Zhuang Autonomous Region | |
| 1996—2002 | Member, CPC, Autonomous Regional Committee, Standing Committee Guangxi Zhuang Autonomous Region | |
| 1995—1998 | Secretary, CPC, Autonomous City Committee Guangxi Zhuang Autonomous Region, Nanning City | |
| 1993—1995 | Chairman, Autonomous Regional People's Congress Guangxi Zhuang Autonomous Region, Fangchenggang |
| 08/22/03 | Li Zhaoxing exchanged views over the phone with US Secretary of State Colin Powell on the impending six-party talks. |